Cyclohexane has a high degree of symmetry, and this enables the molecules to pack nicely into a crystalline structure with strong London dispersion forces between them.. Cyclohexene exists in a half-chair conformation. Boiling point of water depending on pressure; Boiling point of gases (table of values) Boiling point and melting of simple substances; Boiling point of metals (table of values) Dielectric constant of liquids, gases and solids (Table) Guidechem provides Cyclohexane chemical database query, including CAS registy number 110-82-7, Cyclohexane MSDS (Material Safety Data Sheet), nature, English name, manufacturer, function/use, molecular weight, density, boiling point, melting point, structural formula, etc. What is internal and external criticism of historical sources? It is a cycloalkane and a volatile organic compound. ; Cramers, C.A., High precision capillary gas chromatography of hydrocarbons, Chromatographia, 7(3), 1974, 99-106. umn class: Standard non-polar; Column diameter: 0.20 mm; Column length: 25 m; Column type: Capillary; Start T: 60 C; CAS no: 110827; Active phase: HP-1; Carrier gas: N2; Data type: Kovats RI; Authors: Bangjie, C.; Yijian, G.; Shaoyi, P., Calculation of retention indices at an assigned temperature from temperature programmed data, Chromatographia, 25(6), 1988, 539-542. umn class: Standard non-polar; Column length: 2 m; Column type: Packed; Start T: 120 C; CAS no: 110827; Active phase: SE-30; Data type: Kovats RI; Authors: Pascal, J.C.; Heintz, M.; Druilhe, A.; Lefort, D., Relations entre structure chimique et grandeurs de retention. Markush Class. Chromatogr., 91, 1974, 623-631. umn class: Semi-standard non-polar; Column length: 1.8 m; Column type: Packed; Start T: 40 C; CAS no: 110827; Active phase: Squalane; Substrate: Untreated celite; Data type: Kovats RI; Authors: Evans, M.B., Retention indices of solutes on squalane, dinonyl phthalate, and polyethylene glycol 400, J. Pure cyclohexane in itself is rather unreactive, being a non-polar, hydrophobic hydrocarbon. ; Strense, T.V. ; Ettre, L.S., Retention index values of hydrocarbons on open-tubular columns coated with methylsilicone liquid phases, Chromatographia, 15(10), 1982, 625-630. umn class: Standard non-polar; Column diameter: 0.31 mm; Column length: 91.4 m; Column type: Capillary; Start T: 50 C; CAS no: 110827; Active phase: SF-96; Phase thickness: 0.20 um; Data type: Kovats RI; Authors: Johansen, N.G. ; Petrova, V.I., Temperature dependence of cycloalkane's retention and its using in identification of structure, Gazovaya Khromatografiya, 15, 1971, 18-26. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 17.5 m; Column type: Capillary; Start T: 50 C; CAS no: 110827; Active phase: OV-1; Phase thickness: 0.15 um; Data type: Kovats RI; Authors: Johansen, N.G. Molecular Weight. Quim., 83, 1987, 56-58. umn class: Standard non-polar; Column diameter: 0.5 mm; Column length: 100 m; Column type: Capillary; Start T: 80 C; CAS no: 110827; Active phase: SE-30; Data type: Kovats RI; Authors: Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Similarly, cyclohexane has very close cystalline packing which may account for its low melting point. ; Kopecni, M.M. and g.c.-m.s. Anal. ; Ratcliffe, N.M.; Spencer-Phillips, P.T.N., Identification of volatiles generated by potato tubers (Solanum tuberosum CV: Maris Piper) infected by Erwinia carotovora, Bacillus polymyxa and Arthrobacter sp., Plant Pathol., 48, 1999, 345-351. ass: Standard non-polar; Column diameter: 0.20 mm; Column length: 50 m; Column type: Capillary; Heat rate: 1 K/min; Start T: 30 C; End T: 100 C; Start time: 6 min; CAS no: 110827; Active phase: OV-101; Carrier gas: Helium; Phase thickness: 0.50 um; Data type: Normal alkane RI; Authors: Orav, A.; Kailas, T.; Muurisepp, M.; Kann, J., Composition of the oil from waste tires. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.22 mm; Column length: 50 m; Column type: Capillary; Heat rate: 1 K/min; Start T: -30 C; End T: 240 C; CAS no: 110827; Active phase: Ultra-2; Carrier gas: He; Phase thickness: 0.33 um; Data type: Linear RI; Authors: Haynes, P.C., Jr.; Pitzer, E.W., Disengaging solutes in shale- and petroleum-derived jet fuels by altering GC programmed temperature rates, J. Hi. How do I reset my key fob after replacing the battery? ; Laub, R.J., Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-101 and SP-2100 Polydimethylsiloxane Solvents, J. Hi. Comm., 6(10), 1983, 577-580. umn class: Semi-standard non-polar; Column diameter: 0.23 mm; Column length: 100 m; Column type: Capillary; Start T: 42.5 C; CAS no: 110827; Active phase: Squalane; Carrier gas: N2; Data type: Kovats RI; Authors: Engewald, W.; Epsch, K.; Graefe, J.; Welsch, Th., Molekulstruktur und retentionsverhalten. Chromatogr., 351, 1986, 65-75. ass: Standard non-polar; Column diameter: 0.20 mm; Column length: 25 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 60 C; End T: 240 C; CAS no: 110827; Active phase: OV-101; Carrier gas: Nitrogen; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zenkevich, I.G. Chromatogr. ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Res. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 110827; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Stereoisomeres cyclohexaniques, Chromatographia, 7(5), 1974, 236-245. umn class: Standard non-polar; Column type: Capillary; Start T: 60 C; CAS no: 110827; Active phase: OV-101; Data type: Kovats RI; Authors: Chien, C.-F.; Furio, D.L. Cyclohexanol occurs as colorless crystals with a weak camphorlike odor. Boiling Points of Common Organic Solvents (°C) Acetic acid 118 Acetone 56 Acetonitrile 82 Anisole 154 Benzene 80 Bromobenzene 156 tert.-Butanol 82 Carbon disulfide 46 Carbon tetrachloride 77 Chlorobenzene 132 Chloroform 61 Cyclohexane 81 Dibutyl ether 142 o -Dichlorobenzene 181 1,2-Dichloroethane 84 Dichloromethane 40 Res. More is more! Vol.17, 1972, 14-25. umn class: Semi-standard non-polar; Column type: Packed; Start T: 80 C; CAS no: 110827; Active phase: Squalane; Carrier gas: H2; Data type: Kovats RI; Authors: Fernandez-Sanchez, E.; Garcia-Dominguez, J.A. II. 114.3±13.0 °C. Chem., 21, 1968, 1125-1141. umn class: Semi-standard non-polar; Column type: Packed; Start T: 150 C; CAS no: 110827; Active phase: Squalane; Data type: Kovats RI; Authors: Schomburg, G., Gas-Chromatographische Retentionsdaten und Struktur Chemischer Verbindungen. Comm., 6, 1983, 328-332. umn class: Semi-standard non-polar; Column length: 1 m; Column type: Packed; Start T: 100 C; CAS no: 110827; Active phase: Squalane; Carrier gas: He; Substrate: Chromaton N-AW-HMDS; Data type: Kovats RI; Authors: Nabivach, V.M. ; Kudryashov, S.Y. Cyclohexanol. Two organic compounds A and B have the same molecular formula C 6 H 12. ; Kuningas, K.R. Chem., 45(1), 2004, 144-150. umn class: Semi-standard non-polar; Column type: Capillary; Start T: 70 C; CAS no: 110827; Active phase: Squalane; Carrier gas: N2; Data type: Kovats RI; Authors: Sojak, L., Separation and identification of isomeric hydrocarbons by capillary gas chromatography and hyphenated spectrometric techniques, Petroleum & Coal, 46(3), 2004, 1-35. umn class: Semi-standard non-polar; Column type: Capillary; Start T: 70 C; CAS no: 110827; Active phase: Squalane; Carrier gas: H2; Data type: Kovats RI; Authors: Sojak, L., Separation and identification of isomeric hydrocarbons by capillary gas chromatography and hyphenated spectrometric techniques, Petroleum & Coal, 46(3), 2004, 1-35. umn class: Semi-standard non-polar; Column length: 3.3 m; Column type: Packed; Start T: 130 C; CAS no: 110827; Active phase: C78, Branched paraffin; Carrier gas: He; Data type: Kovats RI; Authors: Dallos, A.; Sisak, A.; Kulcsar, Z.; Kovats, E., Pair-wise interactions by gas chromatography VII. Melting Point (MP), Cyclohexane changes its state from solid to liquid at 6.47°C (43.646°F or 279.62K) Boiling Point (BP), Cyclohexane changes its state from liquid to gas at 80.7°C (177.26°F or 353.85K) Molecular formula: C 6 H 12. Chim. & Chromatogr. Emergency Overview Extremely flammable liquid and vapor. characteristic melting point and boiling point. ; Eisen, O.G., Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 200 C; Start time: 10 min; CAS no: 110827; Active phase: DB-Wax; Carrier gas: He; Data type: Kovats RI; Authors: Umano, K.; Shibamoto, T., Analysis of headspace volatiles from overheated beef fat, J. Agric. ; Laub, R.J., Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-1 and SE-30 Polydimethylsiloxane Solvents, J. Hi. Cyclohexanol is also used as an intermediate for rubber chemicals, plasticizers, cyclohexamine, and pesticides. It is slightly soluble in water and soluble in alcohol, acetone, benzene, ethanol, ethyl ether, olive oil, and carbon tetrachloride. [6], On an industrial scale, cyclohexane is produced by hydrogenation of benzene in the presence of a Raney nickel catalyst. Acta, 609, 2008, 24-36. ass: Standard non-polar; Column type: Capillary; CAS no: 110827; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Xu, X.; Chu, S.; Song, N., Application of chromatographic studies of air pollution in China, J. Chromatogr. Chromatogr., 126, 1976, 63-83. umn class: Semi-standard non-polar; Column length: 2.4 m; Column type: Packed; Start T: 130 C; CAS no: 110827; Active phase: Apolane; Carrier gas: He; Substrate: Chromosorb; Data type: Kovats RI; Authors: Riedo, F.; Fritz, D.; Tarjan, G.; Kovats, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. V. Influence of electronic effects and column polarity on retention index, J. Chromatogr. Res. Chim. Chim. A series of temperatures of pure cyclohexane are obtained as it cools down from room temperature through its freezing point in an ice bath. ' '' ''' - -- --- ---- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Prod. Analysis of low-molecular-weight hydrocarbons and nitriles with a CP-Sil-5 CB WCOT capillary column, J. ; Hua, R.L. PET 01 - Petroleum, 2004. ass: Standard non-polar; Column type: Capillary; CAS no: 110827; Active phase: OV-101; Data type: Normal alkane RI; Authors: Shibamoto, T., Retention Indices in Essential Oil Analysis, in Capillary Gas Chromatography in Essential Oil Analysis, Sandra, P.; Bicchi, C., ed(s), Hutchig Verlag, Heidelberg, New York, 1987, 259-274. ass: Standard non-polar; Column type: Capillary; CAS no: 110827; Active phase: SE-30; Data type: Normal alkane RI; Authors: Vinogradov, B.A., Production, composition, properties and application of essential oils, 2004. ass: Standard non-polar; Column diameter: 0.53 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 40 C; End T: 260 C; Start time: 5 min; CAS no: 110827; Active phase: DB-1; Carrier gas: He; Phase thickness: 3 um; Data type: Normal alkane RI; Authors: J&W Scientific, Solvent Retention Data, 2003. class: Standard non-polar; Column diameter: 0.1 mm; Column length: 20 m; Column type: Capillary; Description: 40C(0.4min) =>10C/min=> 110C=>20C/min =>260C (1min); CAS no: 110827; Active phase: DB-1; Carrier gas: He; Phase thickness: 0.4 um; Data type: Normal alkane RI; Authors: LECO Corporation, Rapid qualitative GC/TOFMS analysis of unleaded gasoline, 2003. class: Standard non-polar; Column diameter: 0.1 mm; Column length: 20 m; Column type: Capillary; Description: 40C(0.4min) => 10C/min =>110C =>20C/min =>260C (1min); CAS no: 110827; Active phase: DB-1; Carrier gas: He; Phase thickness: 0.4 um; Data type: Normal alkane RI; Authors: LECO Corporation, Rapid qualitative GC/TOFMS analysis of a petroleum refinery reformate standard, 2003. class: Standard polar; Column diameter: 0.25 mm; Column length: 50 m; Column type: Capillary; Description: 45 0C (15 min) ^ 3 0C/min -> 75 0C ^ 5 0C/min -> 180 0C (10 min); CAS no: 110827; Active phase: Supelcowax 10; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Soria, A.C.; Martinez-Castro, I.; Sanz, J., Some aspects of dynamic headspace analysis of volatile components in honey, Foog Res. It has a melting point of 25.15°C, a boiling point of 161.1°C, and a density of 0.942 g/cm3 at 30°C. ; Kuningas, K.R. Hence, cyclohexane has a higher boiling point. Res. The 6-vertex edge ring does not conform to the shape of a perfect hexagon. Air - Speed of Sound - Speed of sound in air at standard atmospheric pressure with temperatures ranging -40 to 1000 o C (-40 to 1500 o F) - Imperial and SI Units. t-butyl alcohol. Chromatogr., 472, 1989, 129-143. umn class: Standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Start T: 65 C; CAS no: 110827; Active phase: OV-1; Carrier gas: He; Phase thickness: 0.52 um; Data type: Kovats RI; Authors: Guan, Y.; Kiraly, J.; Rijks, J.A., Interactive retention index database for compound identification in temperature-programmed capillary gas chromatography, J. Comm., 4, 1981, 539-543. umn class: Standard non-polar; Column type: Capillary; Start T: 70 C; CAS no: 110827; Active phase: SE-30; Carrier gas: H2; Data type: Kovats RI; Authors: Chien, C.-F.; Kopecni, M.M. Sci., 8, 1970, 95-102. umn class: Semi-standard non-polar; Column length: 1 m; Column type: Packed; Start T: 160 C; CAS no: 110827; Active phase: Apiezon L; Substrate: Chromaton N-AW; Data type: Kovats RI; Authors: Kurbatova, S.V. This chemical is highly flammable and can react with other oxidizing materials. III. Acta, 56(3), 1973, 1159-1164. umn class: Semi-standard non-polar; Column length: 5 m; Column type: Packed; Start T: 100 C; CAS no: 110827; Active phase: Apiezon L; Data type: Kovats RI; Authors: Rohrschneider, L., Eine methode zur charakterisierung von gaschromatographischen trennflussigkeiten, J. An alicyclic hydrocarbon comprising a ring of six carbon atoms; the cyclic form of hexane, used as a raw material in the manufacture of nylon. J., 81, 2005, 184-190. umn class: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Start T: 20 C; CAS no: 110827; Active phase: HP-1; Phase thickness: 0.25 um; Data type: Kovats RI; Authors: Wang, Y.; Liu, J.; Li, N.; Shi, G.; Jiang, G.; Ma, W., Preliminary study of the retention behavior for different compounds using cryogenic chromatography at different initial temperatures, Microchem. 69oC toluene b.p. Chromatogr. J., 81, 2005, 184-190. umn class: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Start T: 0 C; CAS no: 110827; Active phase: HP-1; Phase thickness: 0.25 um; Data type: Kovats RI; Authors: Wang, Y.; Liu, J.; Li, N.; Shi, G.; Jiang, G.; Ma, W., Preliminary study of the retention behavior for different compounds using cryogenic chromatography at different initial temperatures, Microchem. Stereoisomeres cyclohexaniques, Chromatographia, 7(5), 1974, 236-245. umn class: Standard polar; Column length: 2 m; Column type: Packed; Start T: 140 C; CAS no: 110827; Active phase: Carbowax 20M; Data type: Kovats RI; Authors: Pascal, J.C.; Heintz, M.; Druilhe, A.; Lefort, D., Relations entre structure chimique et grandeurs de retention. How do you seal a quadrant shower cubicle? Molecular Weight: 90.12. Aspiration hazard if swallowed - can enter lungs and cause damage. PHMSA's 2016 Emergency Response Guidebook provides first responders with a go-to manual to help deal with hazmat transportation accidents during the critical first 30 minutes. Chromatogr., 7(2), 1989, 88-92. ass: Standard non-polar; Column type: Capillary; CAS no: 110827; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Feng, H.; Mu, L.-L., Quantitative structure-retention relationships for alkane and its derivatives based on electrotopological state index and molecular shape index, Chem. Correlation between the retention index, physicochemical properties and molecular structure, Chromatographia, 13(2), 1980, 93-100. umn class: Semi-standard non-polar; Column length: 5 m; Column type: Packed; Start T: 100 C; CAS no: 110827; Active phase: Squalane; Data type: Kovats RI; Authors: Rohrschneider, L., Eine methode zur charakterisierung von gaschromatographischen trennflussigkeiten, J. & Chromatogr. 80.73 °C / 760 mmHg Kaye & Laby (No … CopyCopied, CSID:7787, http://www.chemspider.com/Chemical-Structure.7787.html (accessed 16:46, Dec 13, 2021) ; Sutton, DL., Kovats retention indices of selected hydrocarbons through C10 on bonded phase fused silica capillaries, J. Hi. Res. Markush Group. Retention indices of amines in some polar and unpolar stationary phases, Latv. ; Dutoit, J.-Cl. of St. Petersburg Univ. Find the freezing point of a solution of 110 mg of pentane, C5H12, in 16.45 g of cyclohexane. ; Ettre, L.S., Retention index values of hydrocarbons on open-tubular columns coated with methylsilicone liquid phases, Chromatographia, 15(10), 1982, 625-630. umn class: Standard non-polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 50 C; CAS no: 110827; Active phase: OV-101; Carrier gas: N2; Phase thickness: 1.39 um; Data type: Kovats RI; Authors: Pacakova, V.; Hoch, K.; Smolkova, E., The Effect of Instrumentation on the Precision of Retention Indexes, Chromatographia, 6(7), 1973, 320-324. umn class: Standard non-polar; Column type: Capillary; Start T: 30 C; CAS no: 110827; Active phase: SE-30; Carrier gas: H2; Data type: Kovats RI; Authors: Chien, C.-F.; Kopecni, M.M. & Chromatogr. Res. Fraction boiling at yp to 160 0C, Proc. Stereoisomeres cyclohexaniques, Chromatographia, 7(5), 1974, 236-245. umn class: Standard non-polar; Column type: Capillary; Start T: 80 C; CAS no: 110827; Active phase: OV-101; Data type: Kovats RI; Authors: Chien, C.-F.; Furio, D.L. [7] Producers of cyclohexane account for approximately 11.4% of global demand for benzene. what liquid is this? Cyclohexanol occurs as colorless crystals with a weak camphorlike odor. Boiling point (at 760 mm Hg): 80.7 degrees C (177.26 degrees F) 3. ; Willis,B.J., ed(s), Elsevier, New York, 1988, 981-998. umn class: Standard polar; Column length: 2 m; Column type: Packed; Start T: 75 C; CAS no: 110827; Active phase: Carbowax 20M; Carrier gas: N2; Substrate: Kieselgur (60-100 mesh); Data type: Kovats RI; Authors: Goebel, K.-J., Gaschromatographische Identifizierung Niedrig Siedender Substanzen Mittels Retentionsindices und Rechnerhilfe, J.